Keywords: CEST / APT / NOE, Molecular Imaging, AI, Deep Learning, Unsupervised Learning, Bloch-McConnell, Differentiable Physics
Motivation: MRF-based quantification of semi-solid MT/CEST proton-exchange requires a computationally demanding dictionary synthesis/matching. Recently reported unsupervised learning alternatives were incompatible with pulsed clinical CEST and multi-pool imaging.
Goal(s): To develop a training-set-free MRF reconstruction method, learning directly from the acquired data via pulsed-saturation-compatible physical modeling.
Approach: A differentiable multi-pool Bloch-McConnel simulator was designed and embedded within a test-time learning framework. Validation was performed using L-arginine phantoms and a human subject at 3T.
Results: The method enabled quantitative MT/CEST reconstruction in ~1 minute. The resulting maps were highly correlated with ground-truth in-vitro (Pearson’s r>0.95). In-vivo, semi-solid volume fractions were in agreement with MRF-based maps (r~0.8).
Impact: A one-stop-shop for semisolid MT and CEST MRF reconstruction was developed, enabling a training-set-free rapid quantification of exchange parameters on clinical scanners. This accessible approach could help a variety of Bloch-fitting applications to benefit from deep learning through differentiable spin-physics.
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Fig. 1: Overview of explored methods. (a.) MRF pipeline (reference method). Raw non-steady-state MT/CEST images, as well as any auxiliary (T1,2, B0,1) maps serve as inputs to an MLP (c), trained on a large dictionary (synthesized over hours/days) to reconstruct MT/CEST parameters. (b.) NBMF pipeline (ours). A test-subject MRF data serves as both the input for an MLP decoder (c) and as the regression target for the decoder-simulator circuit. Convergence yields a reconstruction for the test subject, and an inference-ready neural decoder. (d.) Solvers' features/limitations.
Fig. 2: Typical in-vitro scan reconstruction. (a, b.) L-arginine concentration and amine proton exchange rate (ksw) maps generated using NBMF. (c.) Ground truth concentrations (d.) Ground truth pH and QUESP-estimated exchange rates. An excellent agreement was obtained between NBMF and ground truth: r(ksw)=0.97, r([L-arg])=0.95 (r - Pearson's correlation across all voxels).
Fig. 3: Statistical analysis of the in-vitro study. (a.) NBMF-based exchange rates compared to QUESP and a base-catalyzed proton exchange model. (b.) L-arginine concentrations estimated across the different vials (A-G). The green triangles represent the ground truth.