Keywords: Contrast mechanisms: Contrast agents, Contrast mechanisms: Relaxometry, Contrast mechanisms: CEST & MT
During this lecture the speaker will delve into the physics and chemistry of MR contrast agents and how they enhance image quality, as well as their various applications in clinical practice. Attendees will gain a deeper understanding of the different types of contrast agents used in T1W and T2W MRI, including metal-based agents and iron-oxide nanoparticles, and their advantages and limitations. The lecture will also cover safety concerns on the use of Gadolinium-based CAs and possible alternatives/reduction strategies will be presented. Other classes of CAs beyond Gd and iron-oxide nanoparticles, such as CEST and hyperpolarized agents, will also be introduced.1) P. Caravan, J. J. Ellison, T. J. McMurry, R. B. Lauffer, Gadolinium(III) Chelates as MRI Contrast Agents: Structure, Dynamics, and Applications, Chem. Rev. 1999, 99, 2293-2352
2) J. Wahsner, E. M. Gale, A. Rodríguez-Rodríguez, P. Caravan, Chemistry of MRI Contrast Agents: Current Challenges and New Frontiers, Chem. Rev. 2019, 119, 2, 957–1057.
3) E. Gianolio, E. Di Gregorio, S. Aime, Chemical Insights into the issues of Gd retention in the brain and other tissues upon administration of Gd-containing MRI contrast agents, EurJIC, 2019, 2, 137-151.
3) E. Lancelot, J.S. Raynaud, P. Desche, Current and Future MR Contrast Agents Seeking a Better Chemical Stability and Relaxivity for Optimal Safety and Efficacy, Investigative Radiology, 2020, 55,578-588.