Michiel Cottaar1, Benjamin C. Tendler1, Wenchuan Wu1, Karla L. Miller1, and Saad Jbabdi1
1WIN@FMRIB, University of Oxford, Oxford, United Kingdom
Synopsis
We propose a novel sequence that adds a second asymmetric spin echo after
a standard Stejskal-Tanner sequence. This allows the estimation of the off-resonance frequency
of the diffusion-weighted signal due to the myelin magnetic susceptibility. Varying
the orientation of the diffusion-weighting gradient dephases different fibre
populations. In simulations we show that for a sufficiently high b-value
(>~3 ms/μm2), the intra-axonal water will dominate leading to a
simple relation between the myelin-induced frequency shift and the log g-ratio.
This allows the difference in log g-ratio between crossing fibres to be
measured and hence estimate the myelination of individual crossing tracts.
Introduction
While a
wide variety of myelin-sensitive MRI contrasts1,2 have been proposed, these only give voxel-averaged estimates. Resolving this into myelin estimates for
individual crossing fibres would allow more precise estimates of the
myelination of individual tracts in health and disease3.
Here we
propose to measure the myelin-induced frequency offset after diffusion weighting. Diffusion-weighting
makes the MRI sequence sensitive to fibre orientations. However, due to its
short T2, myelin water becomes invisible after diffusion weighting on most scanners1,2 This invalidates combining
diffusion-weighting with those myelin MRI contrasts that rely on detecting the myelin
water properties directly (i.e., its short T16,7, T2*8, T24,9, or magnetisation transfer10–12). However, the magnetic field shift
induced by the magnetic susceptibility of myelin also affects the intra- and
extra-axonal water13, which are still visible after
diffusion weighting. We measure this field shift as a phase offset in an asymmetric-spin echo acquisition after diffusion-weighting.
Here we
present and test with Monte Carlo simulations the novel sequence and an
analysis method to extract the difference in myelination between crossing
fibres.Sequence
Up to the
first echo planar imaging (EPI) readout, the proposed sequence is identical to
a Stejskal-Tanner
14 sequence (although planar diffusion
encoding could also be used). After the first readout an extra refocusing
pulse is added followed by a second EPI readout, which is delayed with a time $$$t_{\rm{}phase}$$$ from the second
spin echo (Figure 1A).
The phase difference between the first and second readout is determined by the off-resonance frequency, but unaffected by phase offsets caused by bulk
motion during the diffusion weighting
15,16.
Imaging the off-resonance frequency after diffusion-weighting
has two distinct advantages:
- In a crossing fibre configuration,
different gradient orientations can be used to distinguish between the myelin-induced
off-resonance frequency for each fibre population.
- The diffusion weighting increases
the relative contribution of intra-axonal water compared with extra-axonal
water17 (with its less restricted
diffusion). This simplifies the analysis,
because the frequency offset due to myelin susceptibility ($$$f_{\rm{}myelin}$$$) has a flat profile within the axons (Figure 2B)13
and has a simple relation with the g-ratio
(i.e., ratio of inner over outer axon
diameter): $$\frac{f_{\rm{}myelin}}{f_{\rm{}Larmor}}=-\frac{3}{4}\chi_{\rm{}A}\langle{}\log{}g\rangle{}\sin^2\theta,\tag{1}$$ where
$$$\theta$$$ is the angle
between the axons and the main magnetic field orientation,
$$$\chi_{\rm{}A}$$$ is the
anisotropic susceptibility of myelin (-100 ppb13), and $$$\langle{}\log{}g\rangle$$$ is the average log g-ratio.
Simulations
We ran
Monte Carlo simulations18 of crossing fibres in Camino19 (see geometry in Figure 2). The signal magnitude is
attenuated by the diffusion-weighted gradients, T2 (80 ms20), and T2’ (50 ms21) dephasing (Figure 1B).
Ideally, the phase would only be affected by the myelin-induced off-resonance frequency (Figure 1C), but in practice we also expect off-resonance frequency due
to non-myelin sources ($$$f_{\rm{}other}$$$) and random phase offsets due to even small motion
during the diffusion-weighting ($$$\phi_{{\rm{}DW}}(\hat{\nu})$$$)15,16 (Figure 1D). We minimize the echo time for each b-value assuming
an EPI readout time of 50 ms and the maximum gradient strength (80 mT/m) and slew
rate (200 T/m/s) of a 3T Siemens Prisma scanner.Fitting the fibre myelination
For diffusion data with a single b-value, the complex signal at the first spin-echo readout ($$$S_{\rm{}SE}$$$) is fitted by:
$$S_{\rm{}SE}(b,\hat{\nu})=\sum_kA_{{\rm{}SE};k}e^{-b\hat{\nu}\mathbf{B}_k\hat{\nu}}e^{i\phi_{{\rm{}DW}}(\hat{\nu})}\tag{2},$$
where we estimate
for each crossing fibre $$$k$$$ the signal
amplitude ($$$A_{{\rm{}SE};k}$$$), the demeaned diffusion tensor ($$$\mathbf{B}_k=\mathbf{D}_k-{\rm{}MD}_k\mathbf{I}$$$)22, and the phase from movement during
the diffusion-weighting ($$$\phi_{{\rm{}DW}}(\hat{\nu}$$$). Because this signal is at a spin-echo, there is no
phase accumulation due to off-resonance.
Simultaneously,
we fit the second asymmetric spin echo signal ($$$S_{\rm{}ASE}$$$) using:
$$S_{\rm{}ASE}(b,\hat{\nu})=\sum_kA_{{\rm{}ASE};k}e^{-b\hat{\nu}\mathbf{B}_k\hat{\nu}}e^{i[\phi_{{\rm{}DW}}(\hat{\nu})+2\pi{}f_kt_{\rm{}phase}]}\tag{3},$$
Both readouts are
fitted with a common demeaned diffusion tensor ($$$\mathbf{B}_k$$$), but a different amplitude ($$$A_{{\rm{}SE};k}$$$ and $$$A_{{\rm{}ASE};k}$$$). The off-resonance frequency for each crossing fibre ($$$f_k$$$) is fitted to the phase offset between readouts (Figure 3).
For each fibre population
the frequency ($$$f_k$$$) will have a contribution from myelin ($$$f_{{\rm{}myelin};k}$$$; eq. 1) and other susceptibility sources ($$$f_{\rm{}other}$$$). For interleaving fibres, non-myelin susceptibility
sources should affect all fibre orientations equally, so we can compare this frequency
between two crossing fibres (labeled $$$k$$$ and $$$l$$$) to get:
$$f_l-f_k=f_{{\rm{}myelin};l}-f_{{\rm{}myelin};k}=\frac{3}{4}\chi_{\rm{}A}f_{\rm{}Larmor}\left(\langle{}\log{}g\rangle_k\sin^2\theta_k-\langle{}\log{}g\rangle_l\sin^2\theta_l\right)\tag{4}$$
Estimates of the g-ratio per fibre orientation can be obtained by
repeating the measure for different head orientations (i.e., varying $$$\theta$$$) or by adding an extra constraint by estimating the
average g-ratio across the whole voxel through different means23,24.Accuracy and precision
A biased estimate of the frequency difference
was found in the simulations due to the extra-axonal water contribution at low b-values
(Figure 4A) and phase wrapping errors at long $$$t_{\rm{}phase}$$$ (Figure 4B).
When selecting a b-value and $$$t_{\rm{}phase}$$$, these inaccuracies have to be traded off with the
low SNR at high b-values (Figure 4C) and the lower phase accumulation at
low $$$t_{\rm{}phase}$$$ (Figure 4D).Discussion
While the
details of the simulation shown here depend on the assumed microstructural
geometry, relaxation properties, and scanner properties, the general features
of the proposed sequence illustrated should generalise more broadly. For fast
readouts (i.e., $$$<t_{\rm{}phase}$$$) the sequence can be shortened by removing the second
refocusing pulse.
For
interleaving crossing fibres, the off-resonance frequency difference will be purely driven by the difference in the g-ratio between the fibre populations
(modulated by angle with the main magnetic field), which allows this difference to be estimated. This represents a first step to not just estimating a voxel-averaged g-ratio, but a fibre-population specific g-ratio.Acknowledgements
We thank
Matt Hall, Matteo Bastiani, and Stamatios Sotiropoulos for helpful discussions.References
1. Alexander, A. L. et al. Characterization of cerebral white matter
properties using quantitative magnetic resonance imaging stains. Brain
Connect 1, 423–46 (2011).
2. Heath, F., Hurley, S. A.,
Johansen-Berg, H. & Sampaio-Baptista, C. Advances in noninvasive myelin
imaging. Dev Neurobiol 78, 136–151 (2018).
3. Edgar, J. M. & Griffiths, I. R.
White Matter Structure: A Microscopist’s View. in Diffusion MRI: From
Quantitative Measurement to In-vivo Neuroanatomy (eds. Johansen-Berg, H.
& Behrens, T. E. J.) (Elsevier Science, 2014).
4. Stanisz, G. J. & Henkelman, R. M.
Diffusional anisotropy of T2 components in bovine optic nerve. Magn Reson
Med 40, 405–10 (1998).
6. Travis, A. R. & Does, M. D.
Selective excitation of myelin water using inversion-recovery-based
preparations. Magn Reson Med 54, 743–7 (2005).
7. De Santis, S., Barazany, D., Jones, D.
K. & Assaf, Y. Resolving relaxometry and diffusion properties within the
same voxel in the presence of crossing fibres by combining inversion recovery
and diffusion-weighted acquisitions. Magn Reson Med 75, 372–80
(2016).
8. Du, Y. P. et al. Fast multislice
mapping of the myelin water fraction using multicompartment analysis of T2
decay at 3T: A preliminary postmortem study. Magn. Reson. Med. 58,
865–870 (2007).
9. Whittall, K. P. & MacKay, A. L.
Quantitative interpretation of NMR relaxation data. J. Magn. Reson. 1969
84, 134–152 (1989).
10. Henkelman, R. M., Stanisz, G. J. &
Graham, S. J. Magnetization transfer in MRI: a review. NMR Biomed 14,
57–64 (2001).
11. Avram, A. V., Guidon, A. & Song, A.
W. Myelin water weighted diffusion tensor imaging. Neuroimage 53,
132–8 (2010).
12. Sled, J. G. Modelling and interpretation
of magnetization transfer imaging in the brain. Neuroimage 182,
128–135 (2018).
13. Wharton, S. & Bowtell, R. Fiber orientation-dependent
white matter contrast in gradient echo MRI. Proc Natl Acad Sci USA 109,
18559–64 (2012).
14. Stejskal, E. O. & J.E, T. Spin
Diffusion Measurements: Spin Echoes in the Presence of a Time Dependent Field
Gradient. J Chem Phys (1965) doi:10.1063/1.1695690.
15. Anderson, A. W. & Gore, J. C.
Analysis and correction of motion artifacts in diffusion weighted imaging. Magn
Reson Med 32, 379–87 (1994).
16. Miller, K. L. & Pauly, J. M.
Nonlinear phase correction for navigated diffusion imaging. Magn. Reson.
Med. 50, 343–353 (2003).
17. Veraart, J., Fieremans, E. & Novikov,
D. S. On the scaling behavior of water diffusion in human brain white matter. Neuroimage
185, 379–387 (2019).
18. Hall, M. G. & Alexander, D. C.
Convergence and parameter choice for Monte-Carlo simulations of diffusion MRI. IEEE
Trans Med Imaging 28, 1354–64 (2009).
19. Cook, P. et al. Camino:
open-source diffusion-MRI reconstruction and processing. in 14th scientific
meeting of the international society for magnetic resonance in medicine
vol. 2759 2759 (Seattle WA, USA, 2006).
20. Whittall, K. P. et al. In vivo
measurement of T2 distributions and water contents in normal human brain. Magn.
Reson. Med. 37, 34–43 (1997).
21. Alonso-Ortiz, E., Levesque, I. R. &
Pike, G. B. Impact of magnetic susceptibility anisotropy at 3 T and 7 T on
T2*-based myelin water fraction imaging. Neuroimage 182, 370–378
(2018).
22. Dell’Acqua, F. et al. A
model-based deconvolution approach to solve fiber crossing in
diffusion-weighted MR imaging. IEEE Trans Biomed Eng 54, 462–72
(2007).
23. Stikov, N. et al. In vivo
histology of the myelin g-ratio with magnetic resonance imaging. Neuroimage
118, 397–405 (2015).
24. Campbell, J. S. W. et al. Promise
and pitfalls of g-ratio estimation with MRI. Neuroimage 182, 80–96
(2018).