VDMP-CEST MRI can spatiotemporally monitor disease progression in a mouse model of multiple sclerosis. Lower VDMP-CEST signals corresponded to a decreased lipid and metabolite content in the peri-ventricular region of the brain, characteristic of the disease, with magnetic resonance spectroscopy used as validation.
Experimental autoimmune encephalomyelitis (EAE) was induced in C57Bl/6 mice (n=4) by i.p. injection of 250 ng of pertussis toxin and s.c. injection of 300 μg of MOG35-55 in complete Freud’s adjuvant supplemented with 4 mg/ml tuberculin on day 0 and day 2. Naïve mice (n=4) did not receive these injections. Mice were monitored daily and assessed for paralysis using the following clinical scoring system: 0=healthy, 1=tail paralysis, 2=mild hindlimb paralysis, 3=total hindlimb paralysis, 4=forelimb paralysis, and 5=moribund/death.
Mice were imaged biweekly with T2-weighted and VDMP CEST MRI using a horizontal bore 11.7T scanner (Biospec, Bruker). For transmission, a 72 mm volume resonator was used. For MRI acquisition, 2x2 and 4x1 phased array coils were used for the brain and spinal cord, respectively. For T2-weighted images, a TE=30 ms, TR=2.5 s, RARE factor = 8, NA=4, and a slice thickness=0.7 mm was used. For VDMP-CEST MRI, 32 pulse-exchange modules with a 2 ms pulse width, a B1 = 46.8 μT, ,ten delays (0 to 150 ms), and a slice thickness=2.0 mm were used. Significance was defined at p<0.05 using ANOVA.
Regional differences in VDMP-CEST signal were seen in the brain and spinal cord of EAE-induced mice. In brain frontal cortex, the lateral ventricular region exhibited lower VDMP-CEST signal than the parenchyma-rich region (Figure 1). In the lumbar spinal cord, the white matter region also had a lower VDMP-CEST signal compared to grey matter region (not shown).
Temporal changes in VDMP-CEST signal were seen in the peri-ventricular region of the brain in EAE-induced mice (Figure 2). VDMP-CEST signal was lower in this region during the acute phase (day 24 post-induction) compared to that observed at disease onset (day 15 post-induction) or before induction (day 0). Reduction of VDMP-CEST signal in the peri-ventricular region corresponded to a reduced presence of glutamine/glutamate (Glx), N-acetyl aspartate (NAA), and free lipids in magnetic resonance spectroscopy (MRS, Figure 3), in agreement with the metabolic changes revealed using mass spectroscopy3. Phantom images of brain metabolites at 20 mM concentration revealed that glutamine/glutamate is a major contributor of the VDMP-CEST signal (Figure 4).
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