Macromolecule-suppressed J-difference-edited MRS of GABA is extremely sensitive to B0 offsets. Relatively small frequency shifts (~10 Hz) may cause unwanted co-editing of macromolecules, to the extent that the edited ‘GABA’ signal appears negative in-vivo. We demonstrate an approach to measure transient field shifts arising from gradient-related eddy currents, and present a way to minimize these effects in order to restore correct editing.
All experiments were performed on a Philips 3T Achieva scanner, using a MEGA-PRESS sequence (Figure 1A) with TR/TE = 2000/80 ms; 20-ms sinc-Gaussian editing pulses (bandwidth 53 Hz) at 1.9 and 1.5 ppm 2, symmetrically arranged about 1.7 ppm (the frequency of the coupled MM resonance) to suppress the co-edited MM signal. Two male subjects gave informed consent to participate.
Initial in-vivo acquisition: MEGA-PRESS spectra were acquired twice from the inferior frontal gyrus and primary sensorimotor areas (27-mL voxels, 320 averages). Data were processed using the ‘Gannet’ program.6
Determination of eddy-current-induced frequency offsets: MEGA-PRESS saturation-offset series were acquired from an NAA phantom by varying the symmetry-point offset (in steps of 0.05 ppm). The intensity of the NAA signal at 2.01 ppm in the difference spectrum was measured. For correct frequency calibration at 3T, the zero-crossing of the NAA difference integral should appear when the symmetry-point has an offset of -353.7 Hz from the water frequency, corresponding to the difference between the chemical shifts of NAA and room-temperature water (Figure 1B). The deviation of the measured zero-crossing from this expected zero-crossing is defined as Δf, which quantifies transient changes in B0 at the time the editing pulse is applied - a correctly calibrated experiment has Δf=0.
Voxel orientation effects: In order to investigate the impact of crusher-gradient orientation on editing pulse offsets, saturation-offset series (as above) were acquired for three different crusher gradient (voxel) orientations: no voxel rotation; 45-degree axial rotation; and 45-degree sagittal rotation.
Fixing the crusher-gradient coordinate-frame: Subsequently, the coordinate frame of crusher gradients was decoupled from the voxel orientation and fixed to a 45-degree sagittal rotation. Offset series (as above) were acquired from an unrotated voxel with and without this switch enabled.
Final in-vivo acquisition: MEGA-PRESS data were acquired from a midline parietal region. Acquisition and post-processing were identical to the initial in-vivo acquisitions, except that the coordinate frame of crusher gradients was fixed.
MM-suppressed GABA-editing at 3T is very susceptible to frequency mis-calibration. Net-negative edited signals at 3 ppm may occur for editing pulse Δf >13 Hz (e.g. Fig. 3C in reference 5). The current experiments show a transient field shift of this order of magnitude during the editing pulses, the magnitude of which depends on crusher gradient orientation, unambiguously establishing that the effect is caused by gradient pulses. These eddy-current effects, while relatively small and transient, significantly affect the performance of highly selective spectral editing experiments. The effects can be minimized by fixing the crusher-gradient orientation to one with the least eddy current effects.
Magnitude-, duration- and orientation-dependence of eddy-current-related offset are likely to be heavily scanner-dependent. The transient frequency shift during editing pulses may be due to sub-optimal eddy-current compensation, as much as due to the eddy currents themselves.
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