Short-T2* magnetization (order of [0.1,1ms]) can relax appreciably during standard-rate excitation pulses, which can bias estimates of relaxation rates formed by fitting to observed signal decay. The effect can, however, be included in an updated model to improve T2* estimation for fast-relaxing signals. Here, a demonstration is presented.
Conventional $$$R_2^*$$$ estimation proceeds by fitting signal progressions acquired over collected echo times $$$\{t_i\}_i$$$ to a model of the form$$f(R_2^*,t_i;\gamma)=g(\gamma)\exp(-{R_2^*}{t_i})\textrm{,}$$where $$$g(\gamma)$$$ is some function describing sequence-determined signal-amplitude dependence upon assumed-known parameters—e.g., tip angle $$$\alpha$$$, repetition time TR—and may include co-estimation parameters—e.g., equilibrium magnetization $$$M_0$$$[4,5]. In terms of $$$R_2^*$$$, $$$f$$$ is a decaying exponential. The fit can be formed by constrained minimization of the squared error between modeled signal and measured signal (C-L-S; also called 'non-linear least-squares' or NLLS)[4,6].
If $$$R_2^*$$$ is significant relative to the $$$B_1$$$ excitation rate, appreciable relaxation occurs during the excitation[3,7,8]. This suggests manipulating excitation amplitude $$$B_1$$$ as a complementary mode of interrogating relaxation. Using the Bloch equation to calculate the effect leads to an update of the fitting model to one of the form$$f(R_2^*,t_i,(B_1,\alpha);\gamma)=\tilde{g}(\gamma)b(R_2^*,B_1,\alpha)\exp(-{R_2^*}{t_i})\textrm{,}$$where $$$b(R_2^*,B_1,\alpha)$$$ describes the Bloch-simulated excitation (Fig.1).
Images of bottle phantoms and rubber structures (Fig.2) were acquired by a dual-echo/dual-excitation 3D UTE sequence (Fig.1), recording four images from each pairing of RF-excitation rate (15$$$^{\circ}$$$ tip at 24.47μT or 3.8228μT) and echo time (40μs or 2.04ms). Bottles contained MnCl$$$_{\textrm{2}}$$$-doped water varied in concentrations, creating a range of different $$$R_2^*$$$ relaxation rates (Fig.2) Exact $$$R_2^*$$$ values in the rubber compounds are unknown, but they are expected to be high (1ms$$$^{-\textrm{1}}$$$ or higher)[9]. The spoiled gradient-echo sequence acquired with (1.25mm)$$$^{\textrm{3}}$$$ resolution at 9$$$\times$$$ undersampling with 6.4ms TR from a 1.5T scanner with an eight-channel receive-only head coil/body transmit coil.
Estimating $$$R_2^*$$$ was undertaken by C-L-S with a soft-baseline function accounting for magnitude/Rician noise[10]. This does not provide the maximum likelihood estimate, but it can perform well[4,5]. This approach is the same as C-L-S used in 'traditional' $$$R_2^*$$$ estimation, except that its signal model is updated to include the Bloch-simulation factor $$$b(R_2^*,B_1,\alpha)$$$. Equilibrium magnetization $$$M_0$$$ was jointly estimated. Voxels with smaller-than-5%-maximum $$$M_0$$$ estimates were masked to 0 in displayed $$$R_2^*$$$ maps (Fig.3).
Estimating $$$R_2^*$$$ is challenging because the exponential decay curve is a relatively 'weak' basis function, in that all decay rates induce the same shape of signal progression. Interrogating signals using different rates of excitation facilitates some easement of the estimation problem in this sense by generating a set of measurements that are 'more orthogonal'. This allows better distinction of short-$$$T_2^*$$$ signals in particular and can improve estimation accuracy. However, making precise estimates of short-$$$T_2^*$$$ signals is still challenging, because with faster decay they effectively permit fewer sampling opportunities. For example, while a moderate-$$$T_2^*$$$ signal acquired using two excitation rates and sampled at two echo times yields four non-zero measurements, a short-$$$T_2^*$$$ (relative to the later echo times) signal yields only two.
The analysis presented here assumes mono-exponential decay (i.e. single-$$$T_2^*$$$-value) in all voxels. In some cases the assumption may not hold; however, with adequate measurements, the same approach—incorporating intra-excitation relaxation effects—can be employed with other, multi-component models.
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