We have developed a CEST FT-phase MRI method that can measure endogenous Amide Proton Transfer (APT) contrast in lung tumors and other tissues that are affected by lung motion. The method monitors the breathing cycle based on the relative phase angle between adjacent pixels, and selects a subset of images during the quiescent period between breaths. The resulting MTRasym contrast of an oscillating egg white phantom, volunteers, and patients with lung tumors showed that CEST FT-phase MRI produced more precise quantitative assessments of APT.
We shortened the APT saturation pulse to 200 msec to adequately sample stages of a normal breathing cycle. We shortened the interval between saturation frequencies to 0.1 ppm so that saturation frequencies next to the saturation frequency being irradiated would be partially saturated. We hypothesized that the CEST spectrum from our pseudo-steady-state CEST FT-phase method would be similar to a standard CEST spectrum acquired with longer steady state saturation, except for the first few saturation points. We performed simulations using the Bloch equations modified for chemical exchange to evaluate this approach, using a range of T1 relaxation times characteristic of human tissues. We tested a phantom of egg whites in a customized motion device that was moved 3 cm/sec, moved back to the original location, paused for 3 sec, and repeated to simulate breathing motion. We also tested a stationary phantom. Three healthy volunteers and three patients diagnosed with lung cancer were scanned using the same CEST FT-phase method. We acquired images with an CEST FT-phase MRI protocol with steady state saturation using a 3 sec saturation at 1 µT and data points from -7 ppm to +7 ppm in 0.2 ppm units, using FISP to acquire each image. Then a CEST-FT phase MRI protocol with pseudo-steady-state saturation was acquired with a 200 msec saturation at 1 µT and data points from -7 ppm to +7 ppm in 0.03 ppm units.
We segmented the temporal series of CEST spectra based on the quiescent period of the breathing cycle (Figure 1). To obtain the breathing cycle, we selected a Region of Interest (ROI) around the liver dome, applied a Fourier transform to the ROI, determined the phase angle difference between the pixel directly above the center of k-space and the center k-space pixel, and applied a series of digital filtering techniques to refine the monitored respiratory cycle. We retained all CEST FT-phase images with a phase angle within one radian of the center of the quiescent period, which corresponded to ~30% of the images. Each CEST spectrum was fit with a single Lorentzian line shape conducive to the spectral shape for direct water saturation to correct for B0 inhomogeneity. Then MTRasym was determined from the final CEST spectrum for each pixel.
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