Chemical Exchange Saturation Transfer (CEST) is an emerging modality offering an enhanced sensitivity for the detection of dilute metabolites with exchangeable protons. To provide quantitative analysis, an acquisition of multiple images per Z-spectrum is required, leading to long acquisition times in practice. In this report we present a novel approach for rapid acquisition of CEST MRI that exploits sparsity in the Z-spectrum domain. Based on ex-vivo and in-vivo data, an acceleration factor of up to R=5 is shown, without significant loss in data accuracy.
All MR data were recorded with a 9.4 T small animal MRI scanner (Bruker BioSpec, Ettlingen, Germany), equipped with a quadrature 80 mm T/R volume resonator (phantom data) and a cryogenically cooled 2x2 phase array (in-vivo mouse brain data). The CEST acquisition was based on the Rapid Acquisition with Refocused Echoes (RARE) sequence. The saturation module consisted of a train of 10-lobe-sinc pulses interleaved with 2 ms spoiler gradients. The following acquisition parameters were used: field of view 25x25 mm2, matrix size: 96x96, RARE factor: 20, partial Fourier: 83%, echo/repetition time: 4/10000ms.
B0 mapping: WASSR CEST8 was used to obtained B0 maps with the same sequence as used for the CEST measurements. Acquisition parameters were: 40 frequency offsets between +/- 2 ppm, saturation pulse duration: 500 ms, number of saturation pulses: 2, B1 = 0.2 μT.
Phantom data: An Eppendorf 1.5 ml vial was filled with a solution of 100 mM Creatine+200 mM Nicotinamide in a saline adjusted to pH = 7 (Sigma Aldrich, Buchs, Switzerland). CEST acquisition parameters were: 120 frequency offsets between +/- 6 ppm, saturation pulse duration: 500 ms, number of saturation pulses: 10, B1 =1.5 μT.
In vivo brain data: All animal experiments were performed with adherence to the Swiss Federal Act on Animal Protection and were approved by the Cantonal Veterinary Office Zurich. A female C57/BL6 mice were used. CEST acquisition parameters were: 40 frequency offsets between +/- 4 ppm, saturation pulse duration: 250 ms, number of saturation pulses: 20, B1 = 2 μT, total scan time: 26 min.
Data reconstruction: The fully sampled data were reconstructed in ParaVision 6.0.1 (Bruker). Retrospective undersampling (acceleration factor R=2,3,5) was performed using either Poisson-like random undersampling (kZ-SPARSE) with the Fourier transform along the Z dimension or using sheared-grid undersampling with subsequent principal component analysis along Z (kZ-PCA)6. Reconstruction using kZ-SPARSE without the Fourier transform along Z was used to study the effect of sparsity in the Z-domain and corresponds to standard Compressed Sensing reconstruction.
The present study has demonstrated potential benefits of accelerating CEST MRI by exploiting sparsity in the Z-domain. Both, kZ-SPARSE and kZ-PCA provided significant improvements in the accuracy of MTR quantification, compared to Compressed Sensing. Some mismatch in the linewidth of the water line was found for reconstruction with kZ-PCA at R=5 (Fig.2A) which is associated with spatiotemporal fidelity issues described previously9. This has, however, no effect on MTR quantification as shown in Fig.3 due to the broad linewidths of Z-spectra recorded in-vivo. kZ-SPARSE outperformed kZ-PCA for R=2, while kZ-PCA showed superior accuracy for R=3 and 5. In conclusion, undersampled CEST MRI with kZ-SPARSE and kZ-PCA allows for fast, robust and accurate acquisition of Z-spectra and hence holds potential to either improve temporal and/or spatial resolution or reduce overall scan times of of CEST MRI.
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