Proton MRS thermometry exploits the property of temperature dependence of water signal. Most of MRS thermometry utilizes partially suppressed water signal or separately measured water signal without water suppression, in addition to the water suppressed signal for metabolites. This work shows that these approaches are either inaccurate or imprecise. The resultant errors may undermine clinically significant temperature changes. Simultaneous or interleaved measurement of unsuppressed water signal and metabolite/lipid signal is desirable.
Data acquisition All data were acquired on a 3T scanner (GE Discovery 750W) with an 8-channel head coil from 10 human subjects after obtaining approval from IRB and informed consent from the participants. The schedule of 1H MRS scan is shown in Figure 1. Scans were performed with PRESS sequence with the following parameters: TR=3s, TE=68ms, spectral width=5000 Hz, FID data points=1024, voxel size=30x25x25 mm3. The voxel was placed in the medial prefrontal cortex. Total MRS scan time was about 90 min.
Data processing We first combined the signals from coil elements. We employed peak picking method for frequency measurement as we found it was more accurate than spectral fitting in our case. We calculated frequency differences between: (1) the two unsuppressed water signals fw1w2, (2) the first two partially suppressed water signals fw1’w2’, and (3) the second unsuppressed water and the first suppressed water fw2w1’. We converted frequency differences in Hz to the “equivalent” temperature differences in oC using the following equation:
ΔTab=97.134(fb - fa)/f0
where f0 is the system frequency in MHz and a/b represents w1,2 or w1’,2’. We calculated the means and standard deviations of {ΔTab}N (where N = 6) of the 6 pairs of the two unsuppressed water signals, the two suppressed water signals, and the 2nd unsuppressed water and the 1st partially suppressed water, respectively, for each of the 10 subjects (Figures 2,3). In ideal case, Δfab and ΔTab should be zero and we therefore termed non-zero values of Δfab and ΔTab as errors of the frequency and the temperature, respectively. We performed T-test and F-test to determine if there are significant differences in the means and the variations of the {ΔTab} among the subjects.
1. Murakami, T., et al., Brain temperature measured by using proton MR spectroscopy predicts cerebral hyperperfusion after carotid endarterectomy. Radiology, 2010. 256(3): p. 924-31.
2. Babourina-Brooks, B., et al., MRS water resonance frequency in childhood brain tumours: a novel potential biomarker of temperature and tumour environment. NMR Biomed, 2014. 27(10): p. 1222-9.
3. Inoue, T., et al., Noninvasive measurement of human brain temperature adjacent to arteriovenous malformation using 3.0T magnetic resonance spectroscopy. Clin Neurol Neurosurg, 2013. 115(4): p. 445-9.
4. Dehkharghani, S., et al., Proton resonance frequency chemical shift thermometry: experimental design and validation toward high-resolution noninvasive temperature monitoring and in vivo experience in a nonhuman primate model of acute ischemic stroke. AJNR Am J Neuroradiol, 2015. 36(6): p. 1128-35.
5. Thrippleton, M.J., et al., Reliability of MRSI brain temperature mapping at 1.5 and 3 T. NMR Biomed, 2014. 27(2): p. 183-90.
6. Dong, Z., Proton MRS and MRSI of the brain without water suppression. Prog Nucl Magn Reson Spectrosc, 2015. 86-87: p. 65-79.
7. Maudsley, A.A., M.Z. Goryawala, and S. Sheriff, Effects of tissue susceptibility on brain temperature mapping. Neuroimage, 2017. 146: p. 1093-1101.