The application of hyperpolarized 13C MRI to non-invasively acquire metabolic images of [1-13C]lactate and 13C-bicarbonate from the injected [1-13C]pyruvate in the brain of metastatic renal cell carcinoma patient, as well as that of 7 healthy volunteers are investigated. Elevated [1-13C]lactate and [1-13C]pyruvate signals were observed from the metastasis, as well as high lactate-to-bicarbonate ratio. The clinical history of the patient suggests that the elevated signals observed in the metastasis may be reflecting the progressive state of the patient’s disease.
Image Acquisition: Written informed consent was obtained from a renal cell carcinoma patient with brain metastasis and 7 healthy volunteers. A 20-gauge intravenous catheter was inserted into the subject’s forearm prior to being positioned supine and head-first in a GE MR750 3.0T MRI scanner (GE Healthcare, Waukesha, WI). The subject’s head was secured upon a fixed head-coil based that could lock into either the 1H receive array or the 13C birdcage to minimize head motion between scans. Using the scanner’s built-in body coil, 1H multi-echo reference data was acquired. A home-made birdcage 13C head coil placed over the subject’s head was used to acquire 13C-signals following the injection of HP [1-13C]pyruvate (0.1 mmol/kg dose at 4 mL/s followed by a 25 mL normal saline flush at 5 mL/s). The 13C signal was acquired with spectral-spatial excitation9 of lactate/bicarbonate/pyruvate resonances (sequentially) followed by a 3D dual-echo EPI (DE-EPI) readout10 (5s TR; axial; 1.5cm isotropic resolution with FOV 24x24x36cm3). The 13C head coil was replaced with a standard 8-channel 1H neurovascular array (Invivo Inc.) and T2-FLAIR (axial, FOV 22×22 cm2, in-plane resolution 0.6875×0.982 mm2, 3 mm slice thickness, TR/TE 8000/120 ms, flip angle 111°) and fast spoiled GRE (axial, FOV 25.6×25.6 cm2, 1 mm-isotropic resolution, TR 7.6 ms, TE 2.9 ms, flip angle 11°) images were acquired for anatomical reference.
Image Analysis: 13C image reconstruction was performed offline using MATLAB R2013a (The MathWorks Inc., MA, Natick, Massachusetts). Data from the 1H multi-echo reference scan was used to correct geometric distortion artefacts from odd/even echo asymmetry, subject-dependent phase errors, and 13C centre frequency calibration error10. The final metabolite images were generated by summing odd/even echoes and summing individual time-resolved images over full 60s acquisition window to improve SNR. Voxel-by-voxel lactate z-scores were computed from the patient’s lactate data, after removing the voxels with the signal below 15% of the maximum lactate signal. The ratio maps of lactate-to-pyruvate and bicarbonate-to-pyruvate were thresholded to remove ratios with unreliable denominators. The resulting 13C metabolic images and ratio maps were overlaid on the corresponding T2-weighted images for anatomical reference in Osirix.
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